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991.
Ihyeok Seo 《Monatshefte für Mathematik》2016,180(4):893-912
In this paper we find a new condition on a real periodic potential for which the self-adjoint Schrödinger operator may be defined by a quadratic form and the spectrum of the operator is purely absolutely continuous. This is based on resolvent estimates and spectral projection estimates in weighted \(L^2\) spaces on the torus, and an oscillatory integral theorem. 相似文献
992.
Sébastien Thiery Céline Declairieux Denis Tondelier Gijun Seo Bernard Geffroy Olivier Jeannin Rémi Métivier Joëlle Rault-Berthelot Cyril Poriel 《Tetrahedron》2014
We report a structure–property relationship study of four 9,9′-spirobifluorene (SBF) derivatives (4-5Pm-SBF, 2-5Pm-SBF, 4-Ph-SBF and 2-Ph-SBF), substituted with either phenyl or pyrimidine at the C2 or C4 position of the SBF core. Structural, thermal, electrochemical and photophysical properties have been examined and correlated to theoretical calculations in order to study the influence of the nature and the position of the substituent. The emission properties of 4- versus 2-substituted SBFs are noticeably different highlighting, in the excited state, the remarkable effect of substitution in ortho position of SBF. All compounds have been used as host material for green dopant in PhOLEDs with very high performances (2-5Pm-SBF: CE>58 cd/A, PE>35 lm/W, EQE>14%). More importantly, the two 4-substituted SBFs have been used as host materials in blue PhOLEDs, displaying high performance and a decrease of VTH for 4-5Pm-SBF due to the incorporation of the electron-withdrawing pyrimidine. 相似文献
993.
We synthesized fluorophores of different sizes attached to azo derivatives, such as thiophene-, naphthalene-, anthracene-, and pyrene-based azo compounds, and studied their photophysical properties. The compounds exhibited strong color and intensity changes in absorption and emission during the structural change from trans to cis, which also resulted in a large Stokes shift and a difference in quantum yield. Depending on their size, the compounds had different rates of transformation from the trans to cis structure: less conjugated (smaller) fluorophore azo compounds showed higher transition rates than more conjugated (larger) ones. 相似文献
994.
Byung Hyun Park Yong Tae Kim Jae Hwan Jung Tae Seok Seo 《Mikrochimica acta》2014,181(13-14):1655-1668
Since the emergence of lab-on-a-chip technology, a variety of chemical and biochemical assays were successfully implemented on microdevice platforms. Among the chip-based applications, genetic analysis based on the polymerase chain reaction (PCR) has been extensively developed in order to accomplish the goal of cheap, rapid, high-throughput, and point-of-care DNA testing. We are summarizing here several formats of the miniaturized PCR systems including the integration of units for sample pretreatment and downstream analytical detection. The various sections cover (a) miniaturized PCR systems, (b) integrated sample pretreatment-PCR microsystems, (c) integrated PCR-detection microsystems, and (d) integrated sample pretreatment-PCR-detection microsystems. Respective microdevices were successfully introduced recently in the form of a fully integrated microsystem for genetic analysis with sample-in-answer-out capability. Contains 120 references. Figure
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995.
996.
Soo Hyeon Bae Yu Fen Zheng Young Hyo Yoo Jeom Yong Kim Sun Ok Kim Min Jung Jang Jae Hong Seo Soo Kyung Bae 《Journal of separation science》2013,36(12):1904-1912
We developed and validated an accurate and sensitive LC–MS/MS method for the simultaneous quantitation of ginsenoside Rg3 and Rh2 epimers (R‐Rg3, S‐Rg3, R‐Rh2, and S‐Rh2) in rat plasma. Analytes were extracted from 0.1 mL aliquots of rat plasma by liquid–liquid extraction, using 2 mL of ethyl acetate. In this assay, dioscin (500 ng/mL) was used as an internal standard. Chromatographic separation was conducted using an Acclaim RSLC C18 column (150 × 2.1 mm, 2.2 μm) at 40°C, with a gradient mobile phase consisting of 0.1% formic acid in distilled water and in acetonitrile, a flow rate of 0.35 mL/min, and a total run time of 20 min. Detection and quantification were performed using a mass spectrometer in selected reaction‐monitoring mode with negative electrospray ionization at m/z 783.4 → 161.1 for R‐Rg3 and S‐Rg3, m/z 621.3 → 161.1 for R‐Rh2 and S‐Rh2, and m/z 867.2 → 761.5 for the internal standard. For R‐Rg3 and S‐Rg3, the lower limit of quantification was 5 ng/mL, with a linear range up to 500 ng/mL; for R‐Rh2 and S‐Rh2, the lower limit of quantification was 150 ng/mL, with a linear range up to 6000 ng/mL. The coefficient of variation for assay precision was less than 10.5%, with an accuracy of 86.4–112%. No relevant cross‐talk or matrix effect was observed. The method was successfully applied to a pharmacokinetic study after oral administration of 400 mg/kg and 2000 mg/kg of BST204, a fermented ginseng extract, to rats. We found that the S epimers exhibited significantly higher plasma concentrations and area under curve values for both Rg3 and Rh2. This is the first report on the separation and simultaneous quantification of R‐Rg3, S‐Rg3, R‐Rh2, and S‐Rh2 in rat plasma by LC‐MS/MS. The method should be useful in the clinical use of ginseng or its derivatives. 相似文献
997.
Elizabeth Suk‐Hang Lam Daniel Ping‐Kuen Tsang Dr. Wai Han Lam Dr. Anthony Yiu‐Yan Tam Dr. Mei‐Yee Chan Prof. Dr. Wing‐Tak Wong Prof. Dr. Vivian Wing‐Wah Yam 《Chemistry (Weinheim an der Bergstrasse, Germany)》2013,19(20):6385-6397
A series of luminescent platinum(II) complexes of tridentate 1,3‐bis(N‐alkylbenzimidazol‐2′‐yl)benzene (bzimb) ligands has been synthesized and characterized. One of these platinum(II) complexes has been structurally characterized by X‐ray crystallography. Their electrochemical, electronic absorption, and luminescence properties have been investigated. Computational studies have been performed on this class of complexes to elucidate the origin of their photophysical properties. Some of these complexes have been utilized in the fabrication of organic light‐emitting diodes (OLEDs) by using either vapor deposition or spin‐coating techniques. Chloroplatinum(II)? bzimb complexes that are functionalized at the 5‐position of the aryl ring, [Pt(R‐bzimb)Cl], not only show tunable emission color but also exhibit high current and external quantum efficiencies in OLEDs. Concentration‐dependent dual‐emissive behavior was observed in multilayer OLEDs upon the incorporation of pyrenyl ligand into the Pt(bzimb) system. Devices doped with low concentrations of the complexes gave rise to white‐light emission, thereby representing a unique class of small‐molecule, platinum(II)‐based white OLEDs. 相似文献
998.
Sammual Yu‐Lut Leung Elizabeth Suk‐Hang Lam Dr. Wai Han Lam Dr. Keith Man‐Chung Wong Prof. Dr. Wing‐Tak Wong Prof. Dr. Vivian Wing‐Wah Yam 《Chemistry (Weinheim an der Bergstrasse, Germany)》2013,19(31):10360-10369
A new class of luminescent alkynylplatinum(II) complexes with a tridentate pyridine‐based N‐heterocyclic carbene (2,6‐bis(1‐butylimidazol‐2‐ylidenyl)pyridine) ligand, [PtII(C^N^C)(C?CR)][PF6], and their chloroplatinum(II) precursor complex, [PtII(C^N^C)Cl][PF6], have been synthesized and characterized. One of the alkynylplatinum(II) complexes has also been structurally characterized by X‐ray crystallography. The electrochemistry, electronic absorption and luminescence properties of the complexes have been studied. Nanosecond transient absorption (TA) spectroscopy has also been performed to probe the nature of the excited state. The origin of the absorption and emission properties has been supported by computational studies. 相似文献
999.
Qian Sun Christopher D. Yerino Yu Zhang Yong Suk Cho Soon-Yong Kwon Bo Hyun Kong Hyung Koun Cho In-Hwan Lee Jung Han 《Journal of Crystal Growth》2009,311(15):3824-3829
This paper reports a study of the effect of NH3 flow rate on m-plane GaN growth on m-plane SiC with an AlN buffer layer. It is found that a reduced NH3 flow rate during m-plane GaN growth can greatly improve the recovery of in situ optical reflectance and the surface morphology, and narrow down the on-axis (1 0 1¯ 0) X-ray rocking curve (XRC) measured along the in-plane a-axis. The surface striation along the in-plane a-axis, a result of GaN island coalescence along the in-plane c-axis, strongly depends on the NH3 flow rate, an observation consistent with our recent study of kinetic Wulff plots. The pronounced broadening of the (1 0 1¯ 0) XRC measured along the c-axis is attributed to the limited lateral coherence length of GaN domains along the c-axis, due to the presence of a high density of basal-plane stacking faults, most of which are formed at the GaN/AlN interface, according to transmission electron microscopy. 相似文献
1000.
A. D. Panov J. H. Adams Jr. H. S. Ahn G. L. Bashinzhagyan J. W. Watts J. P. Wefel J. Wu O. Ganel T. G. Guzik V. I. Zatsepin I. Isbert K. C. Kim M. Christl E. N. Kouznetsov M. I. Panasyuk E. S. Seo N. V. Sokolskaya J. Chang W. K. H. Schmidt A. R. Fazely 《Bulletin of the Russian Academy of Sciences: Physics》2009,73(5):564-567
The final results of processing the data from the balloon-born experiment ATIC-2 (Antarctica, 2002–2003) for the energy spectra of protons and He, C, O, Ne, Mg, Si, and Fe nuclei, the spectrum of all particles, and the mean logarithm of atomic weight of primary cosmic rays as a function of energy are presented. The final results are based on improvement of the methods used earlier, in particular, considerably increased resolution of the charge spectrum. The preliminary conclusions on the significant difference in the spectra of protons and helium nuclei (the proton spectrum is steeper) and the non-power character of the spectra of protons and heavier nuclei (flattening of carbon spectrum at energies above 10 TeV) are confirmed. A complex structure of the energy dependence of the mean logarithm of atomic weight is found. 相似文献